Tandem Mass Spectra Representation Design for Transformer-Based De Novo Peptide Sequencing
thesis · 2026
thesis · 2026. Xinlue Shen
| Date | 2026-07-27 |
| Type | thesis |
| Publisher | MSc thesis |
| Contribution | benchmark |
| Supervisor | Kaizhong Zhang |
| Link | https://hdl.handle.net/20.500.14721/40077 |
Methods and tools
- Casanovo: First Transformer
- DpNovo: Transformer + dynamic programming
- Spectrum representation ablation study: MSc thesis ablation of how MS/MS peaks should be represented for a Transformer de novo sequencer. Holds a Casanovo-style encoder-decoder backbone fixed and varies only the peak embedding: additive m/z-intensity, separated/concatenated m/z and intensity, precursor-normalised (relative) m/z, learnable relative m/z, zero-vector controls, and probability-aware embeddings fed with DpNovo’s signal-vs-noise peak probabilities. Finds that separating peak features beats the additive baseline, relative m/z adds a further gain, and the best result combines external signal probability with intensity and mass features: evidence that input representation, not just architecture, moves the needle on Transformer de novo accuracy.