Generalizable direct protein sequencing with InstaNexus

preprint · bioRxiv · 2025

preprint · bioRxiv · 2025. Marco Reverenna et al. Protein-based therapeutics, such as antibodies and nanobodies, are not encoded in reference genomes…
Date 2025-07-25
Type preprint
Venue bioRxiv
Publisher Cold Spring Harbor Laboratory
Contribution post-processor
DOI 10.1101/2025.07.25.666861
Citations (OpenAlex) 0

Peer-reviewed version: Generalizable Direct Protein Sequencing With InstaNexus (2026-03-02, Molecular & Cellular Proteomics)

Abstract

Protein-based therapeutics, such as antibodies and nanobodies, are not encoded in reference genomes, challenging their accurate characterization via standard proteomics. Current methods rely on indirect inference, fragmented outputs, and labor-intensive workflows, which hinder functional insights and routine application. Here, we present a generalizable, end-to-end workflow for direct protein sequencing, combining streamlined sample preparation, AI-driven de novo peptide sequencing, and tailored assembly to reconstruct contiguous protein sequences. A novel composite scoring framework prioritises longer assemblies and coverage, enhancing accuracy and reducing ambiguity. Validation across diverse protein modalities demonstrates its utility and ability to robustly sequence functionally critical regions of selected proteins. This workflow represents an advance in precision proteomics with promising applications in therapeutic discovery, immune profiling, and protein science.

Authors

  1. Marco Reverenna · Technical University of Denmark
  2. Maike Wennekers Nielsen · Technical University of Denmark
  3. Darian Stephan Wolff · Novonesis, Technical University of Denmark
  4. Elpida Lytra · Technical University of Denmark
  5. Pasquale D. Colaianni · Technical University of Denmark
  6. Anne Ljungars · Technical University of Denmark
  7. Andreas Hougaard Laustsen · Technical University of Denmark
  8. Erwin M. Schoof · Technical University of Denmark
  9. Jeroen Van Goey · InstaDeep Ltd
  10. Timothy P. Jenkins · Technical University of Denmark
  11. Marie V. Lukassen · Technical University of Denmark
  12. Alberto Santos · Technical University of Denmark
  13. Konstantinos Kalogeropoulos · Delft University of Technology, Kavli Institute of Nanoscience, Technical University of Denmark

Methods and tools

  • InstaNexus: End-to-end workflow for reference-free sequencing of full-length protein therapeutics. Multi-protease digestion yields overlapping peptides, InstaNovo sequences them de novo and Winnow rescores, then greedy overlap or de Bruijn graph assembly (default k=7, min overlap 3) reconstructs contigs ranked by a composite score over coverage, N50, scaffold count and identity. Validated on nanobodies, monoclonal antibodies and de novo mini-binders.
  • InstaNovo: Knapsack beam search

Cites (7)

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