Automated Antibody De Novo Sequencing and Its Utility in Biopharmaceutical Discovery

peer-reviewed · Journal of the American Society for Mass Spectrometry · 2017

peer-reviewed · Journal of the American Society for Mass Spectrometry · 2017. K. Ilker Sen et al. Applications of antibody de novo sequencing in the biopharmaceutical industry range from the discovery of new…
Date 2017-05-01
Type peer-reviewed
Venue Journal of the American Society for Mass Spectrometry
Publisher American Chemical Society (ACS)
Contribution algorithm
DOI 10.1007/s13361-016-1580-0
Venue 2-year citedness 2.58

Abstract

Applications of antibody de novo sequencing in the biopharmaceutical industry range from the discovery of new antibody drug candidates to identifying reagents for research and determining the primary structure of innovator products for biosimilar development. When murine, phage display, or patient-derived monoclonal antibodies against a target of interest are available, but the cDNA or the original cell line is not, de novo protein sequencing is required to humanize and recombinantly express these antibodies, followed by in vitro and in vivo testing for functional validation. Availability of fully automated software tools for monoclonal antibody de novo sequencing enables efficient and routine analysis. Here, we present a novel method to automatically de novo sequence antibodies using mass spectrometry and the Supernovo software. The robustness of the algorithm is demonstrated through a series of stress tests. Graphical Abstract ᅟ.

Authors

  1. K. Ilker Sen · Protein Metrics Inc.
  2. Wilfred H. Tang · Protein Metrics Inc.
  3. Shruti Nayak · NYU Langone Medical Center
  4. Yong J. Kil · Palo Alto Research Center, Protein Metrics Inc.
  5. Marshall Bern · Palo Alto Research Center, Protein Metrics Inc.
  6. Berk Ozoglu · Janssen Research and Development, LLC
  7. Beatrix Ueberheide · NYU Langone Medical Center, Rockefeller University
  8. Darryl Davis · Janssen Research and Development, LLC
  9. Christopher Becker · Protein Metrics Inc.

Methods and tools

  • Supernovo: Automated antibody de novo sequencing: finds the closest-matching germline V-J-C sequences by database search, then converges on the true heavy and light chains by iterative wildcard substitution against the MS/MS spectra. Commercial, shipped in Protein Metrics’ Byos platform.

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